Nitrogen: Difference between revisions

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|align=right
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|elementColor=ffe303
|elementColor=f5f5f5
|elName=Nitrogen
|elName=Nitrogen
|elMass=14.0067
|eltrnCfg=1s<sup>2</sup>2s<sup>2</sup>2p<sup>3</sup>
|eltrnCfg=1''s''<sup>2</sup>2''s''<sup>2</sup>2''p''<sup>3</sup>
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|no4= +5
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|properties=colorless gas
|properties=inert, odorless, colorless gas
|compounds= ammonia, oxides, oxyacids, amines, amides
|compounds= ammonia, oxides, oxyacids, amines, amides
|uses= fertilizers, cryogen, required for life
|uses= fertilizers, cryogen, required for life
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'''Nitrogen''' is a [[Chemical elements|chemical element]], typically found as a [[gas]] in its elemental form. It has the [[chemical symbol]] N, [[atomic number]] (number of [[protons]]) ''Z''&nbsp;=&nbsp;7, and a [[Atomic mass#Standard atomic weights of the elements|standard atomic weight]] of 14.0067&nbsp;g/mol.


'''Nitrogen''', a chemical [[element]], symbolized by N, whose individual atoms comprise a nucleus of seven protons, i.e,., it has an [[atomic number]], ''Z'' = 7, meaning the nucleus has a positive electrical charge designated 7 ''e'', with ''e'' representing the unit [[elementary charge]]. Seven electrons in two surrounding cloud-like energy shells charge-balance the seven protons, rendering the atom electrically neutral. The element occupies the seventh position in the [[periodic table]], in virtue of its atomic number. Its nucleus naturally contains either seven neutrons, the isotope designated <sup>14</sup>N (natural abundance 99.632%), or eight neutrons, the isotope designated <sup>15</sup>N (natural abundance 0.368%). Other isotopes of nitrogen lack stability, decaying in a few minutes or fractions of a second. <sup>14</sup>N has an atomic mass (formerly called atomic weight) of 14.0030740052 u, where u is the [[unified atomic mass unit]]; <sup>15</sup>N has an atomic mass of 15.0001088984 u. The averaged atomic mass (also known as standard atomic weight) is 14.0067 u.
Nitrogen has two stable isotopes: <sup>14</sup>N, with a natural abundance of 99.632%, and <sup>15</sup>N, with a natural abundance of 0.368%. Other isotopes of nitrogen are unstable, decaying in a few minutes or fractions of a second. <sup>14</sup>N has an atomic mass of 14.0030740052 u, and <sup>15</sup>N has an atomic mass of 15.0001088984 u.  


Nitrogen has three unpaired electrons in its outermost shell and therefore can form three single covalent bonds with three other atoms, sharing one electron with each, as in NH<sub>3</sub>, ammonia; a single covalent bond with one atom and one double covalent bond with another, as in azo dyes, -N=N-; and, one triple covalent bond, as in N<sub>2</sub>.  No other element has more oxidation states that nitrogen, which can have oxidation states of -3, -2, -1, 0, +1, +2, +3, +4, and +5.
Nitrogen has three unpaired electrons in its outermost shell and therefore can form three single covalent bonds with three other atoms, sharing one electron with each, as in NH<sub>3</sub>, ammonia; a single covalent bond with one atom and one double covalent bond with another, as in azo dyes, -N=N-; and, one triple covalent bond, as in N<sub>2</sub>.  No other element has more oxidation states than nitrogen, which can have oxidation states of -3, -2, -1, 0, +1, +2, +3, +4, and +5.


== Elemental nitrogen ==
== Elemental nitrogen ==
Covalently bonded with itself in a triple bond (sharing six electrons in total), the diatomic gaseous nitrogen molecule, (N<sub>2</sub>), makes up about 78% by volume (75% by mass) of dry air. At the Earth's surface normal temperature and pressure N<sub>2</sub> exists as a gas with no taste, color or odor. The nitrogen molecule is chemically rather inert, it does not burn, does not support combustion and is only slightly soluble in water. At high temperature it combines with [[oxygen]] to form [[NOx|NO<sub>x</sub>]], a generic designation for the class of nitrogen oxides containing NO,  NO<sub>2</sub>, N<sub>2</sub>O, N<sub>2</sub>O<sub>3</sub>, N<sub>2</sub>O<sub>4</sub>, N<sub>2</sub>O<sub>5</sub>, and NO<sub>3</sub>. Several of these oxides are formed during operation of  [[combustion engine]]s. Liquid nitrogen, which boils at -195.8 C, is used as a cryogenic liquid to preserve organic material such as bacterial strains or sperm samples.  It is also used, usually with liquid helium, to cool superconducting magnetic materials for a variety of instruments including mass spectrometers and nuclear magnetic resonance spectrometers.
Covalently bonded with itself in a triple bond (sharing six electrons in total), the diatomic gaseous nitrogen molecule, (N<sub>2</sub>), makes up about 78% by volume (75% by mass) of dry air. At the Earth's surface normal temperature and pressure N<sub>2</sub> exists as a gas with no taste, color or odor. The nitrogen molecule is chemically rather inert, it does not burn, does not support combustion and is only slightly soluble in water. At high temperature it combines with [[oxygen]] to form [[NOx]], a generic designation for the mono-nitrogen oxides NO and NO2 (nitric oxide and nitrogen dioxide) which are formed during many [[combustion]] processes.
 
Liquid nitrogen, which boils at -195.8 C, is used as a cryogenic liquid to preserve organic material such as bacterial strains or sperm samples.  It is also used, usually with liquid helium, to cool superconducting magnetic materials for a variety of instruments including mass spectrometers and nuclear magnetic resonance spectrometers.


Nitrogen is important for living organisms because it is an important element of [[amino acids]], nucleic acids (DNA & RNA) and many other nitrogenous organic compounds. Synthetic fertilizers contain nitrogen obtained from air by the [[Haber process|Haber-Bosch process]], a so-called [[nitrogen fixation]] process.
Nitrogen is important for living organisms because it is an important element of [[amino acids]], nucleic acids (DNA & RNA) and many other nitrogenous organic compounds. Synthetic fertilizers contain nitrogen obtained from air by the [[Haber process|Haber-Bosch process]], a so-called [[nitrogen fixation]] process.


== Ammonia and ammonium salts ==
== Ammonia and ammonium salts ==
[[Ammonia production]] on an industrial-scale uses the [[Haber process|Haber-Bosch process]], in which nitrogen and hydrogen gasses react, in the presence of iron, heat and pressure, to produce ammonia.  Ammonia can also be produced by reacting ammonium salts with excess alkali, as shown in the following equation.
[[Ammonia production]] on an industrial-scale uses the [[Haber process|Haber-Bosch process]], in which nitrogen and hydrogen gasses react, in the presence of iron, heat and pressure, to produce ammonia.  Ammonia can also be produced by reacting ammonium salts with excess alkali, as shown in the following equation:


<b>NH<sub>4</sub><sup>+</sup> + OH<sup>-</sup> &rarr; NH<sub>3</sub> + H<sub>2</sub>O</b>
<b>NH<sub>4</sub><sup>+</sup> + OH<sup>-</sup> &rarr; NH<sub>3</sub> + H<sub>2</sub>O</b>


Ammonia has a very pungent odor.  Because the molecule has a pyramidal structure, it is very polar and can form hydrogen bonds with water so that saturated aqueous ammonia is 15 M.
Ammonia has a very pungent odor.  Because the molecule has a pyramidal structure, it is very polar and can form hydrogen bonds with water so that saturated aqueous ammonia is 15 M.[[Category:Suggestion Bot Tag]]

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Nitrogen
14.0067(2) -3
0
+3
+5
  N
7
1s22s22p3 15,2,p
[ ? ] Non-Metal:
Properties:
inert, odorless, colorless gas
Compounds:
ammonia, oxides, oxyacids, amines, amides
Uses:
fertilizers, cryogen, required for life


Nitrogen is a chemical element, typically found as a gas in its elemental form. It has the chemical symbol N, atomic number (number of protons) Z = 7, and a standard atomic weight of 14.0067 g/mol.

Nitrogen has two stable isotopes: 14N, with a natural abundance of 99.632%, and 15N, with a natural abundance of 0.368%. Other isotopes of nitrogen are unstable, decaying in a few minutes or fractions of a second. 14N has an atomic mass of 14.0030740052 u, and 15N has an atomic mass of 15.0001088984 u.

Nitrogen has three unpaired electrons in its outermost shell and therefore can form three single covalent bonds with three other atoms, sharing one electron with each, as in NH3, ammonia; a single covalent bond with one atom and one double covalent bond with another, as in azo dyes, -N=N-; and, one triple covalent bond, as in N2. No other element has more oxidation states than nitrogen, which can have oxidation states of -3, -2, -1, 0, +1, +2, +3, +4, and +5.

Elemental nitrogen

Covalently bonded with itself in a triple bond (sharing six electrons in total), the diatomic gaseous nitrogen molecule, (N2), makes up about 78% by volume (75% by mass) of dry air. At the Earth's surface normal temperature and pressure N2 exists as a gas with no taste, color or odor. The nitrogen molecule is chemically rather inert, it does not burn, does not support combustion and is only slightly soluble in water. At high temperature it combines with oxygen to form NOx, a generic designation for the mono-nitrogen oxides NO and NO2 (nitric oxide and nitrogen dioxide) which are formed during many combustion processes.

Liquid nitrogen, which boils at -195.8 C, is used as a cryogenic liquid to preserve organic material such as bacterial strains or sperm samples. It is also used, usually with liquid helium, to cool superconducting magnetic materials for a variety of instruments including mass spectrometers and nuclear magnetic resonance spectrometers.

Nitrogen is important for living organisms because it is an important element of amino acids, nucleic acids (DNA & RNA) and many other nitrogenous organic compounds. Synthetic fertilizers contain nitrogen obtained from air by the Haber-Bosch process, a so-called nitrogen fixation process.

Ammonia and ammonium salts

Ammonia production on an industrial-scale uses the Haber-Bosch process, in which nitrogen and hydrogen gasses react, in the presence of iron, heat and pressure, to produce ammonia. Ammonia can also be produced by reacting ammonium salts with excess alkali, as shown in the following equation:

NH4+ + OH- → NH3 + H2O

Ammonia has a very pungent odor. Because the molecule has a pyramidal structure, it is very polar and can form hydrogen bonds with water so that saturated aqueous ammonia is 15 M.